Yeah you wish your truck was on 48" spring pin centers, that would mean that all you need to do to run that van axle under your frame is slap some 1/2" spacer plates between the frame rails and the spring hangers (van spring perch width is actually 49" and not 50").
Unfortunately pickup-bed perch width is 45" (just verified it too), so if you got a pickup-framed truck you'll have to either cut the van perches off and weld new ones on or just space the rear hangers 2" out from the frame rails. If you got the cab-chassis frame, then that uses spring perch width of about 40" or so, in which case you should be able to just weld new perches onto the van axle and leave the old ones in place.
That said, yes, definitely do get that axle off your neighbor. Its WMS is only about 1/2" narrower than that of a pickup truck dually axle so for all intents and purposes the wheels will be in the exact same place as if it were a factory DRW pickup bed. How goofy would it look? Imagine your rear wheels sitting 3" further out (per side) than they sit now. That's where they will be with that axle. Oh, make sure you get the e-brake cables off that van as well, the ones for the Sterling won't work with the Dana axle.
Btw do keep in mind there are E350s and E450s with DRW dana axles, the E350 uses a D70 with integrated parking brakes and GAWR of 7600 lbs (so 200 more than a factory pickup DRW Sterling) and the E450 is likely a D80 with a driveline brake on the transmission end and GAWR of 9400 lbs. The E450 axle is even wider than the DRW pickup axle, by 2" per side IIRC.