Usually if you have a bad booster you will hear a hissing noise that is very noticeable when you apply the brakes, at least that has been my experience when they fail.
According to the factory service manual that I have, the way to check for a bad booster is to T a vacuum gauge into the line coming off the vacuum pump. Apply and hold the brake pedal. If the vacuum falls below 21 inches HG, it indicates a problem with the booster.
I should also mention that it is a good idea to firstly rule out the new vacuum pump as being bad, because if it isn't producing enough vacuum to begin with, then that test would result in a false positive.