No need for loctite there, if you use any you will hate yourself when it's time to change a belt. If you wanna fell better about it use a springy lock-washer right under the bolt's head, that will also get the threaded end away from the valve cover. From the factory there are neither loctite nor lock-washers tho, just a plain bolt that gets tightened pretty good. I bet yours was left loose during a belt change then just vibrated itself out, I've also forgotten to tighten mine at least once...